Glucosylceramides of pig epidermis: structure determination.

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Glucosylceramides of pig epidermis: structure determination.

Six series of glucosylceramides from pig epidermis have been identified, and their structures have been determined. The structural types identified are: 1, N-acylglucosylsphingosines (33%); 2, N-acylglucosylphytosphingosines (13%); 3, N-(omega-hydroxyacyl)-glucosylsphingosines (3%); 4, N-(alpha-hydroxyacyl)-glucosylphingosines (15%); 5, N-(alpha-hydroxyacyl)-glucosylsphingosines (16%); 6, N-(al...

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Acylglucosylceramides of pig epidermis: structure determination.

The acylglucosylceramides of pig epidermis comprise 56% of the total glucosylceramides and 3.3% of the total epidermal lipid by weight. Contrary to an earlier report on this lipid, the amide-linked fatty acid is not a dihydroxypentatriacontadienoic acid; rather, the fatty acids are a series of long chain omega-hydroxy acids consisting of 58% saturates, 35% monoenes, and 7% dienes, with predomin...

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Linoleate-rich acylglucosylceramides of pig epidermis: structure determination by proton magnetic resonance.

The structure of the linoleate-rich acylglycosylceramides isolated from pig epidermis has been reinvestigated. Gas-liquid chromatographic analysis of the alditol acetates produced from the sugar component indicated that 90% of the hexose is glucose while the remaining 10% is galactose. The predominance of the beta-D-glucosyl group was confirmed by 360 MHz proton magnetic resonance spectroscopy....

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Isolation and characterization of plasma-membrane glycoproteins from pig epidermis.

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Glucosylceramides stimulate murine epidermal hyperproliferation.

Hydrolysis of glucosylceramides (GlcCer) by beta-glucocerebrosidase generates ceramides, critical components of the epidermal permeability barrier. Ceramides also are involved in the regulation of cellular proliferation and differentiation in a variety of cell types. Whereas most studies have focused on ceramides and their sphingoid base metabolites as growth inhibitors, GlcCer apparently acts ...

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ژورنال

عنوان ژورنال: Journal of Lipid Research

سال: 1983

ISSN: 0022-2275

DOI: 10.1016/s0022-2275(20)37896-2